By David H. West and Gregory Yablonsky (Eds.)
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2007). Three approaches can be outlined to choose the formalized thermo dynamic description of the kinetic block of model (7)–(12): (1) the thermo dynamic approach, with additional thermodynamic relations that limit some stages of the studied process mechanism, to be written; (2) the approach related to the transformation of right-hand sides of the kinetic equations and transition from the space of sought variables of the solved problem to the space of thermodynamic potentials, and (3) the approach based on direct use of these sides.
At the same time creating comprehensive descriptions of chemical kinetics and transfer processes one should remember that overcomplication of thermodynamic models leads to the loss of their compara tive advantages over kinetic ones: loss of comparative easiness of setting the initial information (first of all about the process mechanism) and simplicity of the mathematical apparatus employed. 5 Geometrical interpretations Graphical interpretation of MEIS first will be given for a parametric model of elementary reaction of isomerization.
The convex problem is solved by the dynamic programming method and the concave one reduces to calcula tion of flow distribution. The pressure losses in this case are optimized on the tree obtained as a result of assumed flow shutoff at the end points of some branches. M. Kaganovich et al. maximization of an isolated system including a hydraulic network and its environment. , in the network. From the “physico-economic” standpoint convergence of the cho sen method can be explained by the fact that it naturally represents the tendency of an open system with fixed conditions of interaction with the environment to equilibrium, which corresponds to minimum production of both physical and economic entropy.